D-Fructose is converted to D-ribulose using a photochemical Type I ring contraction as the key step in the sequence: isopropylidenation, oxidation, ring contraction, and hydrolysis.
P. M. Collins and P. Gupta, J. Chem. Soc. D, 1969, 1288 DOI: 10.1039/C29690001288
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