Halogenation of dithiocarbamato-complexes of iron, cobalt, antimony, and copper gives compounds in which the dithiocarbamate is oxidised to a positive ion, presumably with an s-tetrathian ring, and the metals are present in halogenated negative ions.
J. Willemse and J. J. Steggerda, J. Chem. Soc. D, 1969, 1123 DOI: 10.1039/C29690001123
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