Below their coalescence temperatures, NN-bistrifluoromethylalkylamines of the type (CF3)2N·CXYZ, show magnetic nonequivalence of their trifluoromethyl groups, which coalesce with free energies of activation in the range 8.4–15.8 kcal./mole.
M. G. Barlow and K. W. Cheung, J. Chem. Soc. D, 1969, 870 DOI: 10.1039/C29690000870
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