Geissoschizine (VI) is proved to undergo rearrangement in Vinca rosea plants to form akuammicine (XIII) together with members of the other three major classes of indole alkaloids.
A. R. Battersby and E. S. Hall, J. Chem. Soc. D, 1969, 793 DOI: 10.1039/C29690000793
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