Saturated C6+ and C8+ carbon ions, generated from primary, secondary, and tertiary bromides or iodides by electron impact, isomerize to a common structure (or structures) prior to reaction via olefin elimination after a lifetime of a few µsec.
W. G. Cole and D. H. Williams, J. Chem. Soc. D, 1969, 784 DOI: 10.1039/C29690000784
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