Volume 64, 1968
From the journal:

Transactions of the Faraday Society

Gas-phase photolysis of hydrogen iodide. Part 3.—Hot atom effects

J. L. Holmes  and  P. Rodgers  

Abstract

The effects of He, H2 and Ar as hot atom moderators in the photolysis of hydrogen iodide in the 2537 Å region of the mercury emission have been studied. The rate constant ratio k3/k2 for reactions H + HI → H2+ I; H + I2→ HI + I has been determined for thermally equilibrated H atoms and has a value 12.0 ± 1 in the temperature range 50–200°C. This result agrees with a value estimated from the thermal hydrogen iodide synthesis.

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Article information

DOI
https://doi.org/10.1039/TF9686402348
Article type
Paper

Trans. Faraday Soc., 1968,64, 2348-2351

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Gas-phase photolysis of hydrogen iodide. Part 3.—Hot atom effects

J. L. Holmes and P. Rodgers, Trans. Faraday Soc., 1968, 64, 2348 DOI: 10.1039/TF9686402348

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