Issue 0, 1968

Aspects of tautomerism. Part I. Environmental and substituent effects on the tautomerism of o-benzoyl benzoic acids

Abstract

Contrary to the common assumption, o-benzoylbenzoic acid exists as a mixture of open and cyclic forms in polar solvents. Substituent and solvent effects on this equilibrium can be described in terms of the Hammett linear free energy relationship.

Article information

Article type
Paper

J. Chem. Soc. B, 1968, 1036-1044

Aspects of tautomerism. Part I. Environmental and substituent effects on the tautomerism of o-benzoyl benzoic acids

M. V. Bhatt and K. M. Kamath, J. Chem. Soc. B, 1968, 1036 DOI: 10.1039/J29680001036

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