Arrhenius parameters have been determined for the addition of trichloromethyl radicals to fluoroethylenes; for the unsymmetric olefins the parameters have been determined for each end of the double bond. [graphic omitted] The determined activation energies are compared with localization energies, and with free valence as calculated from simple Hückel theory.
J. M. Tedder and J. C. Walton, Trans. Faraday Soc., 1966, 62, 1859 DOI: 10.1039/TF9666201859
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