The reaction of alkylthio-tin compounds of the type Me2Sn(SR)2 with nickel salts has resulted in the formation of hexameric nickel mercaptides [Ni(SR)2]6. Reinvestigation of previously reported preparations of high-polymer nickel mercaptides has shown the hexamers to be formed, as well as polymeric material of variable constitution.
E. W. Abel and B. C. Crosse, J. Chem. Soc. A, 1966, 1377 DOI: 10.1039/J19660001377
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