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Issue 6, 2016
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Competing ferro- and antiferromagnetic interactions in a hexagonal bipyramidal nickel thiolate cluster

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Abstract

A new hexagonal bipyramidal Ni8 cluster is reported and its magnetic behaviour is analyzed. The molecular structure consists of a hexagonal wheel capped by two additional apical Ni2+ ions. This structure supports ferromagnetic superexchange interactions between adjacent Ni2+ ions in the wheel and an antiferromagnetic superexchange interaction between the wheel and apical Ni2+ ions.

Graphical abstract: Competing ferro- and antiferromagnetic interactions in a hexagonal bipyramidal nickel thiolate cluster

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Publication details

The article was received on 12 Dec 2015, accepted on 04 Jan 2016 and first published on 05 Jan 2016


Article type: Communication
DOI: 10.1039/C5DT04861C
Citation: Dalton Trans., 2016,45, 2374-2377
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    Competing ferro- and antiferromagnetic interactions in a hexagonal bipyramidal nickel thiolate cluster

    T. Hamaguchi, M. D. Doud, J. Hilgar, J. D. Rinehart and C. P. Kubiak, Dalton Trans., 2016, 45, 2374
    DOI: 10.1039/C5DT04861C

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