A series of (salicylaldiminato)methylnickel complexes efficiently catalyse hydrosilylation of various olefins. The complexes are highly active for secondary hydrosilanes and exhibit excellent selectivity for monohydrosilylation. A possible mechanism, which includes a silylnickel complex as a key active species, is proposed.
V. Srinivas, Y. Nakajima, W. Ando, K. Sato and S. Shimada, Catal. Sci. Technol., 2015, 5, 2081 DOI: 10.1039/C5CY00270B
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