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Issue 87, 2014
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Topotactic elimination of water across a C–C ligand bond in a dense 3-D metal–organic framework

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Abstract

Upon heating, lithium L-malate undergoes topotactic dehydration to form a phase containing the unsaturated fumarate ligand, in which the original 3-D framework remains intact. Insight into this unusual transformation has been obtained by single crystal X-ray diffraction, MAS-NMR, in situ powder X-ray diffraction and DFT calculations.

Graphical abstract: Topotactic elimination of water across a C–C ligand bond in a dense 3-D metal–organic framework

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Publication details

The article was received on 06 Aug 2014, accepted on 08 Sep 2014 and first published on 08 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC06136E
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Citation: Chem. Commun., 2014,50, 13292-13295
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    Topotactic elimination of water across a C–C ligand bond in a dense 3-D metal–organic framework

    H. H.-M. Yeung, M. Kosa, J. M. Griffin, C. P. Grey, D. T. Major and A. K. Cheetham, Chem. Commun., 2014, 50, 13292
    DOI: 10.1039/C4CC06136E

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