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Issue 44, 2012
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Asymmetric H–D exchange reactions of fluorinated aromatic ketones

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Abstract

Chiral bicyclic guanidine catalyzes the asymmetric H–D exchange reactions. Up to 30% ee was achieved. DFT calculations were employed to elucidate and explain the origin of the reaction's stereoselectivity.

Graphical abstract: Asymmetric H–D exchange reactions of fluorinated aromatic ketones

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Publication details

The article was received on 27 Feb 2012, accepted on 30 Mar 2012 and first published on 30 Mar 2012


Article type: Communication
DOI: 10.1039/C2CC31443F
Citation: Chem. Commun., 2012,48, 5479-5481
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    Asymmetric H–D exchange reactions of fluorinated aromatic ketones

    Y. Zhao, X. Lim, Y. Pan, L. Zong, W. Feng, C. Tan and K. Huang, Chem. Commun., 2012, 48, 5479
    DOI: 10.1039/C2CC31443F

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