Issue 13, 2024
From the journal:

Chemical Science

Synthetic utility of functionalized alkylsilyl peroxides for Fe-catalyzed and visible-light-promoted radical transformation†

Jiahao Liu, ORCID logo ab   Shiyong Liu,ab   Zhe Wang,ab   Terumasa Kato,*abc   Yan Liu ORCID logo *ab  and  Keiji Maruoka ORCID logo *abc  

* Corresponding authors

a School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China
E-mail: terumasa.kato.j97@kyoto-u.jp, yanliu@gdut.edu.cn, maruoka.keiji.4w@kyoto-u.ac.jp

b Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, Guangdong University of Technology, Guangzhou 510006, China

c Graduate School of Pharmaceutical Sciences, Kyoto University, Sakyo, Kyoto 606-8501, Japan

Abstract

α-Keto-, β-acetoxy- and β-amidoalkylsilyl peroxides are prepared from various precursors and utilized for Fe-catalyzed and visible-light-promoted radical functionalization with coupling partners under mild conditions with a broad substrate scope.

Graphical abstract: Synthetic utility of functionalized alkylsilyl peroxides for Fe-catalyzed and visible-light-promoted radical transformation

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Article information

DOI
https://doi.org/10.1039/D3SC06857A
Article type
Edge Article
Submitted
21 Dec 2023
Accepted
21 Feb 2024
First published
22 Feb 2024
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2024,15, 4757-4762

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Synthetic utility of functionalized alkylsilyl peroxides for Fe-catalyzed and visible-light-promoted radical transformation

J. Liu, S. Liu, Z. Wang, T. Kato, Y. Liu and K. Maruoka, Chem. Sci., 2024, 15, 4757 DOI: 10.1039/D3SC06857A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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