Issue 31, 2022
From the journal:

Dalton Transactions

Heterolytic carbon–iodine bond cleavage by a palladium(i) metalloradical†

Matthew J. G. Sinclair ORCID logo a  and  Adrian B. Chaplin ORCID logo *a  

* Corresponding authors

a Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry CV4 7AL, UK
E-mail: a.b.chaplin@warwick.ac.uk

Abstract

The well-defined Pd(I) metalloradical [Pd(PtBu3)2]+ reacts with aryl and alkyl iodides at room temperature, yielding [Pd(PtBu3)(μ-I)]2 and phosphonium salts. Pd(II) aryl/alkyl derivates, reflecting net radical oxidative addition of the substrate to the metalloradical, are generated during the reaction and two examples have been isolated and crystallographically characterised.

Graphical abstract: Heterolytic carbon–iodine bond cleavage by a palladium(i) metalloradical

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Article information

DOI
https://doi.org/10.1039/D2DT02152H
Article type
Communication
Submitted
05 Jul 2022
Accepted
10 Jul 2022
First published
11 Jul 2022
This article is Open Access
Creative Commons BY license

Dalton Trans., 2022,51, 11617-11619

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Heterolytic carbon–iodine bond cleavage by a palladium(I) metalloradical

M. J. G. Sinclair and A. B. Chaplin, Dalton Trans., 2022, 51, 11617 DOI: 10.1039/D2DT02152H

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