Luminescent cluster-organic frameworks constructed from predesigned supertetrahedral {Ln4Zn6} secondary building units

Rui Ge; Jin-Hua Liu; Xin-Hao Li; Ling-Yun Li; Yan-Qiong Sun; Zhikai Li; Xin-Xiong Li; Shou-Tian Zheng

doi:10.1039/D1CC02727A

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Luminescent cluster-organic frameworks constructed from predesigned supertetrahedral {Ln₄Zn₆} secondary building units†

Rui Ge,^a Jin-Hua Liu,^a Xin-Hao Li,^b Ling-Yun Li,

^b Yan-Qiong Sun,

^a Zhikai Li,^c Xin-Xiong Li

*^a and Shou-Tian Zheng

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China

^b College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350108, China

^c College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, China
E-mail: lxx@fzu.edu.cn, stzheng@fzu.edu.cn

Abstract

3d–4f heterometallic supertetrahedral clusters with the formula of Ln₄Zn₆(μ₆-O)L₄(CH₃COO)₆(NO₃)₄(CH₃OH)₄(H₂O)₂ (1-Ln, Ln = Eu, Gd, Tb, H₃L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol) have been successfully introduced as stable secondary building units (SBUs) to construct new cluster-organic frameworks with tunable emission, demonstrating a promising strategy for developing new optical materials.

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Article information

DOI: https://doi.org/10.1039/D1CC02727A
Article type: Communication
Submitted: 25 May 2021
Accepted: 14 Jun 2021
First published: 14 Jun 2021

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Chem. Commun., 2021,57, 6927-6930

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Luminescent cluster-organic frameworks constructed from predesigned supertetrahedral {Ln₄Zn₆} secondary building units

R. Ge, J. Liu, X. Li, L. Li, Y. Sun, Z. Li, X. Li and S. Zheng, Chem. Commun., 2021, 57, 6927 DOI: 10.1039/D1CC02727A

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Chemical Communications