In situ detection of heavy metal ions in sewage with screen-printed electrode-based portable electrochemical sensors

Abstract

The rapid development of industrial technologies continuously increases the heavy metal pollution of water resources. Recently, portable electrochemical analysis-based devices for detecting heavy metal ions have attracted much attention due to their excellent performance and low fabrication costs. However, it has proven difficult to accommodate complex testing needs in a cost-effective manner. To address these limitations, we propose a new system for the in situ detection of heavy metals in wastewater using an organic light-emitting diode-based panel to display data in real time and Bluetooth to transmit data to a smartphone for rapid analysis. The fabricated device integrates an in situ signal analysis circuit, a Bluetooth chip, a photocured 3D-printed shell, and an electrode sleeve interface. In addition, a fully screen-printed functional electrode plate containing chitosan/PANi–Bi nanoparticle@graphene oxide multi-walled carbon nanotubes is utilized for the rapid detection of heavy metal ions. This device can perform wireless data transmission and analysis and in situ signal acquisition and processing. The sensor exhibits a high sensitivity (Hg²⁺: 88.34 μA ppm⁻¹ cm⁻²; Cu²⁺: 0.956 μA ppm⁻¹ cm⁻²), low limit of detection (Hg²⁺: 10 ppb, Cu²⁺: 0.998 ppm) and high selectivity during the detection of copper and mercury ions in tap water under non-laboratory conditions, and the results of real-time tests reveal that parameters measured in the field and laboratory environments are identical. Hence, this small, portable, electrochemical sensor with a screen-printed electrode can be effectively used for the real-time detection of copper and mercury ions in complex water environments.