Synthesis and adsorption performance of La@ZIF-8 composite metal–organic frameworks

Abstract

In this study, ZIF-8 with a rhombic dodecahedron structure was prepared by a hydrothermal method. Then La(OH)₃, was successfully loaded onto the ZIF-8 by an immersion deposition method, to form a lanthanide-based metal–organic framework (La@ZIF-8) composites. The structure and properties of La@ZIF-8 were verified by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and zeta potential measurements. The optimum process conditions are discussed within the materials and methods. The effects of initial phosphorus concentration, dosage, pH and contact reaction time on the phosphorus removal performance of the nanomaterial were investigated. The results indicated that La@ZIF-8 exhibited an excellent adsorption capacity (147.63 mg g⁻¹) and its phosphorus removal efficiency could reach as high as 99.7%. Experimental data were interpreted using different adsorption kinetic and isotherm models. The kinetic behavior conformed to the pseudo-second-order kinetic model, which indicated the chemisorption of phosphorus by La@ZIF-8. The adsorption behavior of phosphorus by La@ZIF-8 fitted well to the Langmuir isotherm model, suggesting a monolayer chemical adsorption process. The majority of the adsorbed phosphate could be desorbed by NaOH (2 mol L⁻¹), and the removal efficiency of the recycled La@ZIF-8 reached 90%, even after the fifth cycle. The obtained results demonstrate the great application potential of the prepared La@ZIF-8 as a fascinating adsorbent for the removal of phosphate.