A cascade reaction involving the Zn-catalyzed dearomatization of indoles, base-promoted ring-expansion and intramolecular SNAr reaction has been developed. This process realized a novel, atom economical and efficient synthesis of indoline-fused eight-membered azaheterocycles in a one pot manner.
Y. Mu, Y. Yuan, Y. Wang, M. Xu, Y. Feng, Y. Zhao and Y. Li, Org. Biomol. Chem., 2020, 18, 6916 DOI: 10.1039/D0OB01626H
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