Tuning ferroelectricity and ferromagnetism in BiFeO3/BiMnO3 superlattices

Abstract

Multiferroic materials with multifunctional characteristics play a critical role in the field of microelectronics. In a perovskite oxide, ferroelectric polarization and ferromagnetism usually cannot coexist in a single-phase material at the same time. In this work, we design a superlattice structure composed of alternating BiFeO₃ and BiMnO₃ layers and illustrate how tuning the supercell size of epitaxial BiFeO₃/BiMnO₃ superlattices facilitates ferroelectric polarization while maintaining relatively strong ferromagnetism. A comprehensive investigation reveals that the enhanced ferroelectric polarization of BiMnO₃ layers originates from the induction effect induced by a strong polarization field generated by the adjacent ferroelectric BiFeO₃ layers. For the magnetic behavior, we consider the existence of interfacial antiferromagnetic superexchange interaction of Fe–O–Mn between BiFeO₃ and BiMnO₃ layers in our superlattices. This modulation effect of artificial superlattices provides a platform to accurately control the multiple order parameters in a multiferroic oxide system.