Two large decanuclear hydride clusters of the general formula Ae10H16[N(R)R′]4·(PMDTA)2 (Ae = Ca, Sr) were isolated. Both derivatives feature a [Ae10H16]4+ core, consisting of two edge shared metal octahedra with interstitial hydrides, while the other hydrides cap triangular faces.
J. Martin, J. Eyselein, J. Langer, H. Elsen and S. Harder, Chem. Commun., 2020, 56, 9178 DOI: 10.1039/D0CC04330C
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