A heterodinuclear, formal Au+IPt0 complex with weakly bound alkene ligands

Lukas D. Ernst; Konstantin Koessler; Andreas Peter; Daniel Kratzert; Harald Scherer; Burkhard Butschke

doi:10.1039/D0CC01719A

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A heterodinuclear, formal Au^+IPt⁰ complex with weakly bound alkene ligands†

Lukas D. Ernst,^a Konstantin Koessler,^a Andreas Peter,^a Daniel Kratzert,

^a Harald Scherer^a and Burkhard Butschke

*^a

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* Corresponding authors

^a Institut für Anorganische und Analytische Chemie, Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104 Freiburg, Germany
E-mail: burkhard.butschke@ac.uni-freiburg.de

Abstract

[(Ph₃P)AuPt(nbe)₃][BAr₄^F] (nbe = norbornene) constitutes the first olefin-containing, formal Au^+IPt⁰ complex. The unusual coordination mode and the electronic properties have been analyzed spectroscopically and by calculations. The low binding energy of the nbe ligands make this complex a valuable precursor for formal Au^+IPt⁰ complexes and a candidate for heterobimetallic catalysis.

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Article information

DOI: https://doi.org/10.1039/D0CC01719A
Article type: Communication
Submitted: 05 Mar 2020
Accepted: 02 Apr 2020
First published: 02 Apr 2020

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Chem. Commun., 2020,56, 5350-5353

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A heterodinuclear, formal Au^+IPt⁰ complex with weakly bound alkene ligands

L. D. Ernst, K. Koessler, A. Peter, D. Kratzert, H. Scherer and B. Butschke, Chem. Commun., 2020, 56, 5350 DOI: 10.1039/D0CC01719A

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