Issue 56, 2020

MOF-derived hierarchical 3D bi-doped CoP nanoflower eletrocatalyst for hydrogen evolution reaction in both acidic and alkaline media

Abstract

A 3D hierarchical Bi-doped CoP nanoflower electrocatalyst has been developed based on a MOF self-sacrifice strategy. 3% Bi/CoP delivers a current density of 10 mA cm−2 at low overpotentials of 122 mV in alkaline electrolyte and 150 mV in acidic electrolyte, respectively. DFT calculations demonstrate that Bi doping can synergistically optimize the binding free energy of H* on the CoP (202) facet and ultimately improve the HER performance.

Graphical abstract: MOF-derived hierarchical 3D bi-doped CoP nanoflower eletrocatalyst for hydrogen evolution reaction in both acidic and alkaline media

Supplementary files

Article information

Article type
Communication
Submitted
13 Dec 2019
Accepted
05 Jun 2020
First published
05 Jun 2020

Chem. Commun., 2020,56, 7702-7705

MOF-derived hierarchical 3D bi-doped CoP nanoflower eletrocatalyst for hydrogen evolution reaction in both acidic and alkaline media

L. Guo, X. Bai, H. Xue, J. Sun, T. Song, S. Zhang, L. Qin, K. Huang, F. He and Q. Wang, Chem. Commun., 2020, 56, 7702 DOI: 10.1039/C9CC09684A

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