Pyridine-d5 as a 2H NMR probe for investigation of macrostructure and pore shapes in a layered Sn(IV) phosphonate–phosphate material

Vladimir I. Bakhmutov; Douglas W. Elliott; Gregory P. Wylie; Abraham Clearfield; Aida Contreras-Ramirez; Hong-Cai Zhou

doi:10.1039/C9CC09254D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Pyridine-d₅ as a ²H NMR probe for investigation of macrostructure and pore shapes in a layered Sn(iv) phosphonate–phosphate material†

Vladimir I. Bakhmutov,

*^a Douglas W. Elliott,^a Gregory P. Wylie,^a Abraham Clearfield,*^a Aida Contreras-Ramirez

^a and Hong-Cai Zhou

*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry, Texas A&M University, College Station, TX 77843, USA
E-mail: zhou@chem.tamu.edu

^b Department of Materials Science and Engineering, Texas A&M University, College Station, TX 77843, USA

Abstract

Isotropic and anisotropic motions and molecular states of pyridine-d₅, adsorbed on the surface within the pores of a layered Sn(IV) phosphonate–phosphate material (1) have been characterized thermodynamically and kinetically by solid-state NMR. The data obtained provide formulation of macrostructure and shapes of pores in 1.

Download options Please wait...

Supplementary files

Supplementary information PDF (713K)

Article information

DOI: https://doi.org/10.1039/C9CC09254D
Article type: Communication
Submitted: 10 Dec 2019
Accepted: 21 Feb 2020
First published: 21 Feb 2020

Download Citation

Chem. Commun., 2020,56, 3653-3656

Author version available

Download author version (PDF)

Permissions

Request permissions

Pyridine-d₅ as a ²H NMR probe for investigation of macrostructure and pore shapes in a layered Sn(IV) phosphonate–phosphate material

V. I. Bakhmutov, D. W. Elliott, G. P. Wylie, A. Clearfield, A. Contreras-Ramirez and H. Zhou, Chem. Commun., 2020, 56, 3653 DOI: 10.1039/C9CC09254D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications