Monometallic lanthanide salicylhydrazone complexes exhibiting strong near-infrared luminescence

Abstract

We report the synthesis of monometallic lanthanide complexes supported by one salicylhydrazone ligand. Complexes of neodymium, erbium, and ytterbium have been synthesized, and exhibit near infrared luminescence with modest to high quantum yields. The luminescence of ytterbium is increased by a factor of five when comparing our complex to other salicylhydrazone-supported complexes.