Chiral induction in a pcu-derived network from achiral precursors

Hui Xue; Kang Zhou; Luyao Liu; Dong Wu; Zixiao Hong; Qihui Chen; Feilong Jiang; Daqiang Yuan; Jian Zhang; Maochun Hong

doi:10.1039/C9CC00692C

Chiral induction in a pcu-derived network from achiral precursors†‡

Hui Xue,§^a Kang Zhou,§^a Luyao Liu,^a Dong Wu,^a Zixiao Hong,^b Qihui Chen,

*^a Feilong Jiang,^a Daqiang Yuan,

^a Jian Zhang

*^a and Maochun Hong

*^a

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* Corresponding authors

^a State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou, Fujian, China
E-mail: chenqh@fjirsm.ac.cn, zhj@fjirsm.ac.cn, hmc@fjirsm.ac.cn

^b Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China

Abstract

Rational induction of chirality from achiral systems is one of the most compelling challenges for chemists. Herein, the first chiral net derived from pcu topology has been prepared using the vertex splitting and ligand anchoring strategy, showing a new way to construct chiral frameworks from achiral precursors.

Chemical Communications

Chiral induction in a pcu-derived network from achiral precursors†‡

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Chiral induction in a pcu-derived network from achiral precursors

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