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Significantly Enhanced and Precisely Modeled Thermal Conductivity in Polyimide Nanocomposites by Chemically Modified Graphene via in-situ Polymerization and Electrospinning-hot press Technology

Abstract

Both aminopropyllsobutyl polyhedral oligomeric silsesquioxane (NH2-POSS) and hydrazine monohydrate were utilized to functionalize graphene oxide (GO), and to obtain chemically modified graphene (CMG), which was then used for preparing thermally conductive CMG/polyimide (CMG/PI) nanocomposites via a sequential in-situ polymerization and electrospinning-hot press technology. NH2-POSS molecules were grafted on the GO surface, and CMG were obtained by the reaction between NH2-POSS and GO. The thermally conductive coefficient (λ), glass transition temperature (Tg) and heat resistance index (THRI) of the prepared CMG/PI nanocomposites were all increased with increasing the CMG loading. The λ value of the CMG/PI nanocomposites with 5 wt% CMG was significantly improved to 1.05 W/mK, about 4 times higher than that of pristine PI matrix (0.28 W/mK). The corresponding Tg and THRI values were also increased to 213.0 and 282.3 C, respectively. Moreover, an improved thermally conductive model was proposed and predicted the λ values of the nanocomposites more precisely than those obtained from the typical Maxwell, Russell and Bruggemen classical models.

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Publication details

The article was received on 28 Jan 2018, accepted on 15 Feb 2018 and first published on 15 Feb 2018


Article type: Paper
DOI: 10.1039/C8TC00452H
Citation: J. Mater. Chem. C, 2018, Accepted Manuscript
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    Significantly Enhanced and Precisely Modeled Thermal Conductivity in Polyimide Nanocomposites by Chemically Modified Graphene via in-situ Polymerization and Electrospinning-hot press Technology

    Y. Guo, G. Xu, X. Yang, K. Ruan, T. Ma, Q. Zhang, J. Gu, Y. Wu, H. Liu and Z. Guo, J. Mater. Chem. C, 2018, Accepted Manuscript , DOI: 10.1039/C8TC00452H

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