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Blue versus Yellow Emission in Bipolar Fluorenone Derivatives: Impact of Aggregation and Hydrogen Bonding

Abstract

Three donor-π-acceptor-π-donor multichromophore fluorenone-centered compounds are presented. The π-bridges between fluorenone and carbazole donors contain ethynyl moieties linked to various branched spacing moieties, such as triphenylamine, 1,3,5-triphenylbenzene and 9-phenylcarbazole. Differences in photophysical, photoelectrical, thermal and charge-transporting characteristics of the three compounds are analyzed by means of experimental and density functional theory (DFT) methods. The investigated compounds exhibit good ambipolar charge transport behavior with mobility values exceeding 10-3 cm2 V-1 s-1. The compounds exhibit interesting photoluminescence properties, which are strongly influenced by the important tendency of these compounds in solution to form strongly bounded ground state aggregates. Photoluminescence emission of these materials is found to originate dominantly from intramolecular transitions of π–π*CT nature which experience strong redshift and intensity decrease from the aggregation and intermolecular H-bonds. A slowly evolving equilibrium between strongly aggregated molecules and free ones is observed in THF solutions, resulting in emission color swapping gradually from yellow to blue with drastic intensity increase. Correlation of the aggregation strength with the absorption and emission properties, photoluminescence quantum yield, and the time needed for color swapping is discussed. Furthermore, seldom observed photoluminescence intensity enhancement with the temperature increase was detected in non-polar media.

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Publication details

The article was accepted on 05 Jan 2018 and first published on 08 Jan 2018


Article type: Paper
DOI: 10.1039/C7TC05798A
Citation: J. Mater. Chem. C, 2018, Accepted Manuscript
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    Blue versus Yellow Emission in Bipolar Fluorenone Derivatives: Impact of Aggregation and Hydrogen Bonding

    N. A. Kukhta, D. Y. Volyniuk, J. V. Grazulevicius and G. Sini, J. Mater. Chem. C, 2018, Accepted Manuscript , DOI: 10.1039/C7TC05798A

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