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A new rigid diindenocarbazole donor moiety for high quantum efficiency thermally activated delayed fluorescence emitter

Abstract

We report a new excellent highly conjugated and rigid electron donor (diindolocarbazole) for thermally activated delayed fluorescence (TADF) emitters. The donor acceptor structure with diindolocarbazole donor induce high oscillator strength as well as high probability for the radiative transition, suitable frontier molecular overlap with proper intramolecular charge transfer and large dihedral angle with out-of-plane structure between electron donor and acceptor, resulting in high photoluminescence quantum yield, small singlet-triplet energy splitting, and extremely short delayed fluorescence exciton lifetime. Fabricated organic light emitting diode with new donor applied green emitter exhibits a remarkably high external quantum efficiency of 31.4% without any out-coupling technique and extremely low efficiency roll-off characteristics with the highest luminance of 71160 cd/m2 as well as consequently shows good operational device stability.

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Publication details

The article was received on 24 Oct 2017, accepted on 08 Jan 2018 and first published on 08 Jan 2018


Article type: Communication
DOI: 10.1039/C7TC04852A
Citation: J. Mater. Chem. C, 2018, Accepted Manuscript
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    A new rigid diindenocarbazole donor moiety for high quantum efficiency thermally activated delayed fluorescence emitter

    K. J. Kim, G. H. Kim, R. Lampande, D. H. Ahn, J. B. Im, J. S. Moon, J. K. Lee, J. Y. Lee, J. Y. Lee and J. H. Kwon, J. Mater. Chem. C, 2018, Accepted Manuscript , DOI: 10.1039/C7TC04852A

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