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Nitroxyl radical based conjugated microporous polymers as heterogeneous catalysts for selective aerobic alcohol oxidation

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Abstract

Covalent anchoring of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) on the scaffold of conjugated microporous polymers (CMPs) was achieved via cost-effective FeCl3-catalyzed oxidative polymerization of dicarbazole functionalized TEMPO. These TEMPO-CMPs exhibit excellent catalytic performance for the aerobic oxidation of a wide variety of alcohols under metal-free conditions. In addition, the TEMPO-CMPs could be recycled at least 20 times with good retention of high catalytic activities.

Graphical abstract: Nitroxyl radical based conjugated microporous polymers as heterogeneous catalysts for selective aerobic alcohol oxidation

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Publication details

The article was received on 22 Mar 2018, accepted on 04 May 2018 and first published on 05 May 2018


Article type: Communication
DOI: 10.1039/C8TA02664E
Citation: J. Mater. Chem. A, 2018, Advance Article
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    Nitroxyl radical based conjugated microporous polymers as heterogeneous catalysts for selective aerobic alcohol oxidation

    M. Liu, B. Zhou, L. Zhou, Z. Xie, S. Li and L. Chen, J. Mater. Chem. A, 2018, Advance Article , DOI: 10.1039/C8TA02664E

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