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Research Progress on Vanadium-based Cathode Materials for Sodium Ion Batteries

Abstract

Sodium ion batteries (SIBs) have attracted increasing attention as one of the most promising candidates for cost-effective, high-energy rechargeable batteries. Owing to their high theoretical capacity and energy density, and rich electrochemical interaction with Na+(V2+ ~ V5+), a great number of vanadium-based cathode materials, including vanadium oxides (e.g., V2O5 and VO2), vanadium bronzes (e.g., NaxVO2, NaV3O8, NaV6O15 and δ-NH4V4O10), vanadium-based phosphates (e.g., Na3V2(PO4)3, VOPO4, NaVOPO4, Na7V3(P2O7)4 and Na2(VO)P2O7) and F-containing V-based polyanion (e.g., NaVPO4F, Na3V2(PO4)2F3 and Na3(VOx)2(PO4)2F3-2x), have explored for SIBs. In this review, we mainly summarize the basic structures, modified/optimized structures, synthetic methods and morphology control of V-based cathode materials for SIBs. Additionally, major drawbacks, emerging challenges and some perspectives on the development of V-based cathode materials for SIBs are also concluded.

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Publication details

The article was received on 16 Feb 2018, accepted on 11 Apr 2018 and first published on 11 Apr 2018


Article type: Review Article
DOI: 10.1039/C8TA01627E
Citation: J. Mater. Chem. A, 2018, Accepted Manuscript
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    Research Progress on Vanadium-based Cathode Materials for Sodium Ion Batteries

    Q. Wang, J. Xu, W. Zhang, M. Mao, Z. Wei, C. Cui, L. Wang, Y. Zhu and J. Ma, J. Mater. Chem. A, 2018, Accepted Manuscript , DOI: 10.1039/C8TA01627E

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