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Issue 26, 2018
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Photocatalytic and electrically conductive transparent Cl-doped ZnO thin films via aerosol-assisted chemical vapour deposition

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Abstract

A simple, economical and effective solution-based chemical vapour deposition (CVD) technique, aerosol-assisted CVD, has been successfully applied to produce inexpensive Cl-doped ZnO films using Zn acetate dihydrate and FeCl3. X-ray photoelectron spectroscopy and the increase in cell parameters from powder X-ray diffraction determined that Cl had been doped into the wurtzite ZnO lattice. The Cl-doping had a significant effect on the morphology of the thin films synthesised and resulted in an improvement in the visible light transmission and lower electrical resistance (typical resistivities of doped films ∼10−2 Ω cm). The highest transmittance (% T) of 85% was obtained when 7 mol% FeCl3 was used in the precursor solution and the lowest resistivity of 4.28 ± 0.41 × 10−2 Ω cm was obtained with 5 mol% FeCl3. The greatest photocatalytic activity of stearic acid degradation under UVA irradiation was obtained on using 10 mol% FeCl3, resulting in the highest formal quantum efficiency (FQE) of 3.0 ± 0.1 × 10−4 molecule per photon. These films, therefore, display transparent conducting oxide and photocatalytic properties, giving multifunctional characteristics and promising applications.

Graphical abstract: Photocatalytic and electrically conductive transparent Cl-doped ZnO thin films via aerosol-assisted chemical vapour deposition

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Publication details

The article was received on 09 Feb 2018, accepted on 11 Jun 2018 and first published on 12 Jun 2018


Article type: Paper
DOI: 10.1039/C8TA01420E
Citation: J. Mater. Chem. A, 2018,6, 12682-12692
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    Photocatalytic and electrically conductive transparent Cl-doped ZnO thin films via aerosol-assisted chemical vapour deposition

    A. Jiamprasertboon, M. J. Powell, S. C. Dixon, R. Quesada-Cabrera, Abdullah M. Alotaibi, Y. Lu, A. Zhuang, S. Sathasivam, T. Siritanon, I. P. Parkin and C. J. Carmalt, J. Mater. Chem. A, 2018, 6, 12682
    DOI: 10.1039/C8TA01420E

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