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Issue 16, 2018
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Cationic polymer binder inhibit shuttle effects through electrostatic confinement in lithium sulfur batteries

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Abstract

Irreversible chemical reactions frequently cause capacity fading and poor cycle life in lithium–sulfur (Li–S) batteries due to the formation of irreversible lithium polysulfides. Recently, at the Lawrence Berkeley National Lab, an unexpected cationic polymer strategy resulted in the capture of irreversible polysulfides, which greatly enhanced the Li–S cycling performance. The branched polyethylenimine (PEI) polymer with a high density of amine groups can trap lithium polysulfides through the interaction between –NH in the amine group and soluble Li2Sx. To boost this interaction, cationization was achieved through nucleophilic substitution with CH3I, where the cationic PEI (denoted as MPEII) exhibited enhanced affinity to polysulfides. MPEII attracted not only lithium polysulfide through Li–N and Li–I attraction, but also Sx2− by electrostatic attraction of the positively charged N after cationization. The cell with MPEII binder exhibited better performance than that with PEI in the self-discharge test. It also achieved a high S loading of 6.5 mg cm−2 with high areal capacity of 6.48 mA h cm−2 and consequent areal capacity of 985 mA h g−1 after 10 cycles.

Graphical abstract: Cationic polymer binder inhibit shuttle effects through electrostatic confinement in lithium sulfur batteries

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Publication details

The article was received on 21 Nov 2017, accepted on 19 Mar 2018 and first published on 20 Mar 2018


Article type: Paper
DOI: 10.1039/C7TA10239A
Citation: J. Mater. Chem. A, 2018,6, 6959-6966
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    Cationic polymer binder inhibit shuttle effects through electrostatic confinement in lithium sulfur batteries

    H. Wang, M. Ling, Y. Bai, S. Chen, Y. Yuan, G. Liu, C. Wu and F. Wu, J. Mater. Chem. A, 2018, 6, 6959
    DOI: 10.1039/C7TA10239A

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