Jump to main content
Jump to site search


3D self-supported hierarchical core/shell structured MnCo2O4@CoS arrays for high-energy supercapacitors

Author affiliations

Abstract

MnCo2O4 architectures assembled from well-aligned nanowire or nanosheet arrays have been vertically grown on Ni foam with robust adhesion by in situ hydrothermal growth. Interestingly, the nanostructures of MnCo2O4 can be easily tailored from nanowires to nanosheets by the addition of NH4F at moderate concentrations in a mixed solvent. Further, unique 3D self-supported hierarchical core/shell MnCo2O4@CoS nanowire or nanosheet (MCO-NW@CS or MCO-NS@CS) arrays have been further engineered and synthesized via a subsequent electrodeposition process, which shows that interconnected CoS ultrathin layers as the shell have been uniformly immobilized on the MnCo2O4 arrays to form a novel core/shell structure. The synergic effect of the unique structure and heterogeneity is advantageous to increase the interfacial area, improve the charge accumulation and storage, accelerate the electron and electrolyte ion transfer, and enhance the electrochemical activity of the two components (MnCo2O4 and CoS) when used as an integrated electrode for (asymmetric) supercapacitors. As a result, the MCO-NW@CS or MCO-NS@CS electrodes display greatly improved electrochemical performance including remarkable specific capacitance, outstanding rate capability and good cycling stability. Moreover, the solid-state asymmetric supercapacitor using MCO-NS@CS as the positive active electrode and activated carbon (AC) as the negative active electrode has also achieved high energy density (55.1 W h kg−1 at 477.3 W kg−1). The hierarchical MCO-NW@CS or MCO-NS@CS electrodes with outstanding structural characteristics hold great promise not only in high capacitance applications but also in high energy and power density fields. In addition, to have a deeper understanding of their electrochemical behavior, a combined experimental and density functional theory (DFT) calculation study is also introduced.

Graphical abstract: 3D self-supported hierarchical core/shell structured MnCo2O4@CoS arrays for high-energy supercapacitors

Back to tab navigation

Supplementary files

Publication details

The article was received on 17 Nov 2017, accepted on 21 Dec 2017 and first published on 21 Dec 2017


Article type: Paper
DOI: 10.1039/C7TA10140F
Citation: J. Mater. Chem. A, 2018, Advance Article
  •   Request permissions

    3D self-supported hierarchical core/shell structured MnCo2O4@CoS arrays for high-energy supercapacitors

    G. Liu, B. Wang, T. Liu, L. Wang, H. Luo, T. Gao, F. Wang, A. Liu and D. Wang, J. Mater. Chem. A, 2018, Advance Article , DOI: 10.1039/C7TA10140F

Search articles by author

Spotlight

Advertisements