Jump to main content
Jump to site search

Issue 6, 2018
Previous Article Next Article

Synthesis of porphyrin-based two-dimensional metal–organic framework nanodisk with small size and few layers

Author affiliations

Abstract

A novel porphyrin-based two-dimensional metal–organic framework (MOF) nanodisk with small size and few layers was prepared by coordination chelation between meso-tetra(4-carboxyphenyl)porphine ligand and Zn(II) paddlewheel metal nodes. With 4,4′-biphenyldicarboxylic acid (BPDC) as nucleation modulator, the anisotropic growth of MOF was impeded by the increased steric hindrance, yielding small Zn–TCPP(BP) MOF crystals. The as-prepared MOF nanodisk exhibited good electrocatalytic activity and selectivity towards nitrite due to the independent distribution of the porphyrin molecules in the framework and the sandwich structure of the prepared Zn–TCPP(BP) nanodisk, which increased the accessible active sites.

Graphical abstract: Synthesis of porphyrin-based two-dimensional metal–organic framework nanodisk with small size and few layers

Back to tab navigation

Supplementary files

Publication details

The article was received on 08 Sep 2017, accepted on 07 Jan 2018 and first published on 08 Jan 2018


Article type: Paper
DOI: 10.1039/C7TA07911G
Citation: J. Mater. Chem. A, 2018,6, 2828-2833
  •   Request permissions

    Synthesis of porphyrin-based two-dimensional metal–organic framework nanodisk with small size and few layers

    Y. Zhao, L. Jiang, L. Shangguan, L. Mi, A. Liu and S. Liu, J. Mater. Chem. A, 2018, 6, 2828
    DOI: 10.1039/C7TA07911G

Search articles by author

Spotlight

Advertisements