Jump to main content
Jump to site search


Synthesis of porphyrin-based two-dimensional metal-organic framework nanodisk with small size and less layers

Abstract

A novel porphyrin-based two-dimensional metal-organic framework (MOF) nanodisk with small size and less layers was prepared by coordination chelation between meso-tetra(4-carboxyphenyl)porphine ligand and Zn(II) paddlewheel metal nodes. With 4, 4’-biphenyldicarboxylic acid (BPDC) as nucleation modulator, the anisotropic growth of MOF was impeded by the increased steric hindrance, which led to obtain small Zn-TCPP(BP) MOF crystals. The as-prepared MOF nanodisk exhibited good electrocatalytic activity and selectivity towards nitrite due to the independent distribution of the porphyrin molecules in the framework and sandwich structure of the prepared Zn-TCPP(BP) nanodisk, which increased accessible active sites.

Back to tab navigation

Supplementary files

Publication details

The article was received on 08 Sep 2017, accepted on 07 Jan 2018 and first published on 08 Jan 2018


Article type: Paper
DOI: 10.1039/C7TA07911G
Citation: J. Mater. Chem. A, 2018, Accepted Manuscript
  •   Request permissions

    Synthesis of porphyrin-based two-dimensional metal-organic framework nanodisk with small size and less layers

    Y. Zhao, L. Jiang, L. Shangguan, L. Mi, A. Liu and S. Liu, J. Mater. Chem. A, 2018, Accepted Manuscript , DOI: 10.1039/C7TA07911G

Search articles by author

Spotlight

Advertisements