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Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor

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Abstract

Synthesis of two dimensional (2D) materials mainly relies on interface-templates, exfoliation of layered crystals and surfactant-assistance. Here we have realized another strategy of polymerization in a 2D nano-reactor. As an application of this strategy, a 2D nano-reactor was constructed within a new pillar–layer metal organic framework (MOF) and in this nano-reactor a moderately stable 2D phosphorus material was synthesized from white phosphorus (P4). Our research may provide a new approach for the synthesis of various 2D materials.

Graphical abstract: Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor

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Publication details

The article was received on 28 Mar 2018, accepted on 11 Jun 2018 and first published on 12 Jun 2018


Article type: Edge Article
DOI: 10.1039/C8SC01439F
Citation: Chem. Sci., 2018, Advance Article
  • Open access: Creative Commons BY-NC license
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    Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor

    M. Li, C. Ma, X. Liu, J. Su, X. Cui and Y. He, Chem. Sci., 2018, Advance Article , DOI: 10.1039/C8SC01439F

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