Issue 27, 2018

Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor

Abstract

Synthesis of two dimensional (2D) materials mainly relies on interface-templates, exfoliation of layered crystals and surfactant-assistance. Here we have realized another strategy of polymerization in a 2D nano-reactor. As an application of this strategy, a 2D nano-reactor was constructed within a new pillar–layer metal organic framework (MOF) and in this nano-reactor a moderately stable 2D phosphorus material was synthesized from white phosphorus (P4). Our research may provide a new approach for the synthesis of various 2D materials.

Graphical abstract: Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor

Supplementary files

Article information

Article type
Edge Article
Submitted
28 Mar 2018
Accepted
11 Jun 2018
First published
12 Jun 2018
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2018,9, 5912-5918

Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor

M. Li, C. Ma, X. Liu, J. Su, X. Cui and Y. He, Chem. Sci., 2018, 9, 5912 DOI: 10.1039/C8SC01439F

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