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Issue 5, 2018
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Alkylative kinetic resolution of vicinal diols under phase-transfer conditions: a chiral ammonium borinate catalysis

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Abstract

Herein, we report the first alkylative kinetic resolution of vicinal alcohols realized by cooperative use of a chiral quaternary ammonium salt and an achiral borinic acid. In addition, a catalytic regioselective alkylation of a secondary alcohol in the presence of an unprotected primary one is presented, emphasizing the unique selectivity and potential of this ammonium borinate catalysis.

Graphical abstract: Alkylative kinetic resolution of vicinal diols under phase-transfer conditions: a chiral ammonium borinate catalysis

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Publication details

The article was received on 10 Nov 2017, accepted on 10 Dec 2017 and first published on 12 Dec 2017


Article type: Edge Article
DOI: 10.1039/C7SC04854H
Citation: Chem. Sci., 2018,9, 1231-1235
  • Open access: Creative Commons BY license
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    Alkylative kinetic resolution of vicinal diols under phase-transfer conditions: a chiral ammonium borinate catalysis

    M. Pawliczek, T. Hashimoto and K. Maruoka, Chem. Sci., 2018, 9, 1231
    DOI: 10.1039/C7SC04854H

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