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A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst

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Abstract

Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe33-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.

Graphical abstract: A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst

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Publication details

The article was received on 08 Nov 2017, accepted on 24 Jan 2018 and first published on 24 Jan 2018


Article type: Edge Article
DOI: 10.1039/C7SC04829G
Citation: Chem. Sci., 2018, Advance Article
  • Open access: Creative Commons BY license
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    A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst

    M. Souto, A. Santiago-Portillo, M. Palomino, I. J. Vitórica-Yrezábal, B. J. C. Vieira, J. C. Waerenborgh, S. Valencia, S. Navalón, F. Rey, H. García and G. Mínguez Espallargas, Chem. Sci., 2018, Advance Article , DOI: 10.1039/C7SC04829G

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