A mild fluoride-mediated reaction opens the way to the synthesis of the previously unknown bay-triaminosubstituted and bay-tri(heteroar-N-yl)substituted perylenediimides (PDIs). TriaminoPDIs show bathochromically shifted absorptions reaching near-infrared with increased extinction coefficients when compared to the diamino ones.
D. Gutiérrez-Moreno, Á. Sastre-Santos and F. Fernández-Lázaro, Org. Chem. Front., 2018, 5, 1830 DOI: 10.1039/C8QO00325D
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