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Issue 9, 2018
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Photo-induced, Cu-catalyzed three component azidofluoroalkylation of alkenes with CF3I and RfI as fluoroalkylation reagents

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Abstract

The photo-induced, Cu-catalyzed three component azidofluoroalkylation of alkenes was realized by directly using fluoroalkyl iodides as fluoroalkylation reagents. The reactions showed general and broad abilities, which were effective for the introductions of trifluoromethyl (–CF3), difluoromethyl (CF2CO2Et), and perfluoroalkyl groups (–C4F9, –C6F13, and –C8F17).

Graphical abstract: Photo-induced, Cu-catalyzed three component azidofluoroalkylation of alkenes with CF3I and RfI as fluoroalkylation reagents

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Publication details

The article was received on 02 Feb 2018, accepted on 14 Mar 2018 and first published on 26 Mar 2018


Article type: Research Article
DOI: 10.1039/C8QO00120K
Citation: Org. Chem. Front., 2018,5, 1522-1526
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    Photo-induced, Cu-catalyzed three component azidofluoroalkylation of alkenes with CF3I and RfI as fluoroalkylation reagents

    H. Liu, Q. Guo, C. Chen, M. Wang and Z. Xu, Org. Chem. Front., 2018, 5, 1522
    DOI: 10.1039/C8QO00120K

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