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Issue 9, 2018
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Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO2SCF2H or PhSO2SCF3

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Abstract

A silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols including cyclopropanols, cyclobutanols, cyclopentanols, cyclohexanols and cycloheptanols was described. A variety of common functional groups such as fluoride, chloride, bromide, iodide, trifluoromethyl, cyano and ester groups were compatible.

Graphical abstract: Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO2SCF2H or PhSO2SCF3

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Publication details

The article was received on 01 Feb 2018, accepted on 05 Mar 2018 and first published on 06 Mar 2018


Article type: Research Article
DOI: 10.1039/C8QO00115D
Citation: Org. Chem. Front., 2018,5, 1462-1465
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    Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO2SCF2H or PhSO2SCF3

    B. Xu, D. Wang, Y. Hu and Q. Shen, Org. Chem. Front., 2018, 5, 1462
    DOI: 10.1039/C8QO00115D

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