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Issue 9, 2018
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Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis

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Abstract

The tri- and di-fluoroethylation of alkenes with sulfonium salts, (Ph2S+CH2RF TfO) (RF = CF3 or HCF2), by visible light photoredox catalysis to give tri-/di-fluoroethyl alkenes or methoxytri-/di-fluoroethylation products are described. It was found that varying the reaction solvent led to changes in the reaction path.

Graphical abstract: Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis

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Publication details

The article was received on 25 Jan 2018, accepted on 05 Mar 2018 and first published on 06 Mar 2018


Article type: Research Article
DOI: 10.1039/C8QO00082D
Citation: Org. Chem. Front., 2018,5, 1452-1456
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    Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis

    X. Pan, Y. Zhao, H. Qu, J. Lin, X. Hang and J. Xiao, Org. Chem. Front., 2018, 5, 1452
    DOI: 10.1039/C8QO00082D

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