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Metal-free intermolecular aminochlorination of unactivated alkenes

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Abstract

We report a metal-free method for the synthesis of vicinal chloroamines by intermolecular aminochlorination of unactivated alkenes. This regioselective reaction is inexpensive, atom economical, and environmentally benign and tolerates various functional groups. The aminochlorinated product can be easily deprotected and subsequently transformed into valuable compounds.

Graphical abstract: Metal-free intermolecular aminochlorination of unactivated alkenes

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Publication details

The article was received on 02 Jan 2018, accepted on 09 Feb 2018 and first published on 09 Feb 2018


Article type: Research Article
DOI: 10.1039/C8QO00001H
Citation: Org. Chem. Front., 2018, Advance Article
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    Metal-free intermolecular aminochlorination of unactivated alkenes

    N. Zhu, Y. Li and H. Bao, Org. Chem. Front., 2018, Advance Article , DOI: 10.1039/C8QO00001H

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