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Issue 7, 2018
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Synthesis of chiral γ-aminophosphonates through the organocatalytic hydrophosphonylation of azadienes with phosphites

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Abstract

An organocatalytic enantioselective 1,4-addition of phosphites to azadienes has been successfully developed using quinine as a catalyst, providing an efficient and facile route to optically active γ-aminophosphonates with up to 94% ee.

Graphical abstract: Synthesis of chiral γ-aminophosphonates through the organocatalytic hydrophosphonylation of azadienes with phosphites

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Publication details

The article was received on 27 Dec 2017, accepted on 27 Jan 2018 and first published on 29 Jan 2018


Article type: Research Article
DOI: 10.1039/C7QO01158J
Citation: Org. Chem. Front., 2018,5, 1148-1151
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    Synthesis of chiral γ-aminophosphonates through the organocatalytic hydrophosphonylation of azadienes with phosphites

    Z. Gu, J. Zhou, G. Jiang and Y. Zhou, Org. Chem. Front., 2018, 5, 1148
    DOI: 10.1039/C7QO01158J

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