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Rhodium(III)-catalyzed annulative coupling between arenes and sulfoxonium ylides via C–H activation

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Abstract

The Rh(III)-catalyzed annulative C–H functionalization of arenes with sulfoxonium ylides has been realized. Arenes assisted by diverse nucleophilic directing groups are viable substrates, and the coupling affords structurally diverse fused hetero- and carbocycles under redox-neutral conditions.

Graphical abstract: Rhodium(iii)-catalyzed annulative coupling between arenes and sulfoxonium ylides via C–H activation

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Publication details

The article was received on 17 Nov 2017, accepted on 22 Dec 2017 and first published on 22 Dec 2017


Article type: Research Article
DOI: 10.1039/C7QO01033H
Citation: Org. Chem. Front., 2018, Advance Article
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    Rhodium(III)-catalyzed annulative coupling between arenes and sulfoxonium ylides via C–H activation

    G. Zheng, M. Tian, Y. Xu, X. Chen and X. Li, Org. Chem. Front., 2018, Advance Article , DOI: 10.1039/C7QO01033H

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