The Rh(III)-catalyzed annulative C–H functionalization of arenes with sulfoxonium ylides has been realized. Arenes assisted by diverse nucleophilic directing groups are viable substrates, and the coupling affords structurally diverse fused hetero- and carbocycles under redox-neutral conditions.
The article was received on 17 Nov 2017, accepted on 22 Dec 2017 and first published on 22 Dec 2017
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