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Enantioselective total synthesis of periconiasin A

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Abstract

A concise, enantioselective total synthesis of periconiasin A, a hybrid natural product, has been achieved, featuring a ring closing metathesis (RCM) reaction and a Suzuki coupling to secure a (Z,E,E)-skipped triene system and an intramolecular Diels–Alder (IMDA) reaction to construct the challenging 6–9 fused ring system.

Graphical abstract: Enantioselective total synthesis of periconiasin A

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Publication details

The article was received on 20 Oct 2017, accepted on 30 Nov 2017 and first published on 01 Dec 2017


Article type: Research Article
DOI: 10.1039/C7QO00952F
Citation: Org. Chem. Front., 2018, Advance Article
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    Enantioselective total synthesis of periconiasin A

    Z. Zeng, C. Chen and Y. Zhang, Org. Chem. Front., 2018, Advance Article , DOI: 10.1039/C7QO00952F

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