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Cobalt(III)-catalyzed 1,4-addition of C–H bonds of oximes to maleimides

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Abstract

Oxime directed cobalt-catalyzed arene sp2 C–H bond conjugation addition to maleimide was reported, the reaction showed great tolerance to different functional groups, and various succinimide derivatives were efficiently produced. This protocol exhibited specific reactivity with only producing a mono-C–H bond addition product and no external base was needed, which suggested a unique reactivity of this Co-based catalytic system.

Graphical abstract: Cobalt(iii)-catalyzed 1,4-addition of C–H bonds of oximes to maleimides

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Publication details

The article was received on 03 Aug 2017, accepted on 26 Sep 2017 and first published on 27 Sep 2017


Article type: Research Article
DOI: 10.1039/C7QO00687J
Citation: Org. Chem. Front., 2018, Advance Article
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    Cobalt(III)-catalyzed 1,4-addition of C–H bonds of oximes to maleimides

    X. Chen, J. Ren, H. Xie, W. Sun, M. Sun and B. Wu, Org. Chem. Front., 2018, Advance Article , DOI: 10.1039/C7QO00687J

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