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Issue 6, 2018
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A dendrimer emitter doped in a dendrimer host: efficient thermally activated delayed fluorescence OLEDs with fully-solution processed organic-layers

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Abstract

A thermally activated delayed fluorescence (TADF) carbazole dendrimer (tBuG2TAZ) doped in a carbazole dendrimer host (G3Ph, G4Ph) was employed as an emissive layer (EML) in an OLED device with fully solution processed organic layers. Green (λMAX = 502 nm) emission with a maximum external efficiency (EQEMAX) of 16.1% was achieved when tBuG2TAZ was doped in G3Ph. This value was higher than the previously reported OLED device with a neat film of tBuG2TAZ as an EML because of the higher PLQY due to suppressed concentration quenching. The TADF-active carbazole dendrimer doped in a carbazole host film shows excellent miscibility and solvent resistance to ethanol. On the other hand, when a small molecule (rubrene) was doped in the carbazole dendrimer, significant dissolution of rubrene was observed after rinsing the doped film with ethanol. This shows the importance of the solvent resistivity of a dopant emitter when another film is solution-processed onto the doped film. The “doping dendrimer in dendrimer” concept is a new concept to allow fabrication of fully solution-processed TADF OLEDs.

Graphical abstract: A dendrimer emitter doped in a dendrimer host: efficient thermally activated delayed fluorescence OLEDs with fully-solution processed organic-layers

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Publication details

The article was received on 13 Dec 2017, accepted on 19 Mar 2018 and first published on 03 Apr 2018


Article type: Research Article
DOI: 10.1039/C7QM00579B
Citation: Mater. Chem. Front., 2018,2, 1097-1103
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    A dendrimer emitter doped in a dendrimer host: efficient thermally activated delayed fluorescence OLEDs with fully-solution processed organic-layers

    K. Albrecht, K. Matsuoka, K. Fujita and K. Yamamoto, Mater. Chem. Front., 2018, 2, 1097
    DOI: 10.1039/C7QM00579B

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