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Issue 6, 2018
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In situ synthesis and photocatalytic mechanism of a cyano bridged Cu(I) polymer

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Abstract

A one-dimensional copper(I) nanorod polymer [Cu(L)2·(CN)]n (1) (L = 4(3H)-quinazolone), was formed in situ by C–C bond cleavage of acetonitrile. The in situ synthesis of 1 was analyzed using electron paramagnetic resonance (EPR) spectroscopy and electrospray ionization mass spectrometry (ESI-MS) and its methylene blue (MB) photocatalytic degradation mechanism was revealed from density functional theory (DFT) calculations. The results are helpful for the in situ synthesis of –CN complexes.

Graphical abstract: In situ synthesis and photocatalytic mechanism of a cyano bridged Cu(i) polymer

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Publication details

The article was received on 07 Mar 2018, accepted on 27 Mar 2018 and first published on 28 Mar 2018


Article type: Research Article
DOI: 10.1039/C8QI00205C
Citation: Inorg. Chem. Front., 2018,5, 1282-1287
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    In situ synthesis and photocatalytic mechanism of a cyano bridged Cu(I) polymer

    S. Li, C. Wei, Y. Hu, H. Wu and F. Li, Inorg. Chem. Front., 2018, 5, 1282
    DOI: 10.1039/C8QI00205C

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